Your card does work at Automated Fuel Dispensers ('AFD') - i.e.: it means when payments can be made directly at the fuel pomp payment terminal. However, please note that for security reasons, these merchants can send an authorisation request to your card that can amount up to 130 euros before letting you use the pomp. You will then be allowed to take for a maximum of 130 euros of fuel. You need to have enough funds to cover this authorisation request.
Finally, if the amount of the authorisation is higher than your purchase of fuel, the difference will be automatically credited back to your account within 48 working hours maximum.
Advice: In order to avoid this, you should always pay (when possible) at the counter of the fuel dispenser instead of the automated payment terminal at the pomp.